Deformability characteristics of brazilian laterites     

Jacques De Medina  Laura M. G. Motta  João D. G. Dos Santos 《Geotechnical and Geological Engineering》2006,24(4):949-971

This paper summarizes the resilient and permanent deformation characteristics of laterite gravels, determined by cyclic loading in triaxial tests of compacted specimens. A study of laterite pavements was carried out on eight paved road sections in the state of Mato Grosso. Also reported is the influence of fine sand admixture, specimen size and soaking in two laterite samples from Roraima and Rondônia in the North of Brazil. The experimental relationships of resilient moduli against applied stresses are interpreted empirically for models what may be incorporated in a structural analysis of full depth of laterite pavement.  相似文献   

Mercury speciation and mobilization in contaminated soils of the Valle del Azogue Hg mine (SE,Spain)   总被引：1，自引：0，他引：1  

A. Navarro  H. Biester  J. L. Mendoza  E. Cardellach 《Environmental Geology》2006,49(8):1089-1101

Hg mobilization from contaminated soils and mine wastes was the source of environmental contamination in the Valle del Azogue mining area. We researched solid-phase speciation and aqueous mobility of Hg through Scanning electron microscopy-energy dispersive X-ray spectroscopy and electron probe microanalysis analysis, solid-phase-Hg-thermo-desorption (SPTD) and laboratory column experiments. We found that in contaminated soils and mine wastes, the predominant Hg species was cinnabar (HgS), mainly formed from the weathering of Hg-rich pyrite, and metallic Hg (0) in the matrix, whereas in calcines and tailings the dominant species was metallic Hg (0). The mobilization of Hg in the aqueous phase seems to have originated from the dissolution of elemental Hg (0) present in soils and wastes, reaching concentrations of up to 67 μg l⁻¹, and showing a higher long-term environmental potential risk, in addition to atmospheric emissions.  相似文献   

Simultaneous use of geochemical and geophysical methods to characterise abandoned landfills     

José F. Noguera  Lluís Rivero  Xavier Font  Andrés Navarro  Francisco Martínez 《Environmental Geology》2002,41(8):898-905

. Groundwater sampling and geophysical methods determined a serious contamination problem associated with refilled exploitation sites at the Cal Dimoni area, Llobregat delta, Barcelona, Spain. To characterise this process, hydrogeochemical analyses were performed and showed the following modifications to groundwater chemical composition: increasing pH values, changing redox conditions, significant increases in total organic carbon (TOC) and certain trace elements, and high groundwater conductivity values. Major ion content accumulations were found under the refilled area. In contrast, elements involved in the oxidation–reduction processes, such as iron, manganese and nitrates, clearly diminished. Electromagnetic prospecting methods were also performed and delineated the contamination plume extent. These methods also showed separate sources of contamination, one clearly related to the groundwater–refilled zone leachate interaction, another as a consequence of the manure–accumulation surface site. Geochemical and geophysical methods have shown similar results for locating groundwater contamination sources, and for determining leachate generation mechanisms and flow paths.  相似文献   

PHREEQC and PHREEQCI: Geochemical Modeling with an Interactive Interface     

Laura Toran  David Grandstaff 《Ground water》2002,40(5):462-464

  相似文献   

Crystal-rich mass flow deposits related to the eruption of a sublacustrine silicic cryptodome (Early Permian Collio Basin, Italian Alps)     

Christoph Breitkreuz  Lucio Cortesogno  Laura Gaggero   《Journal of Volcanology and Geothermal Research》2002,114(3-4)

Sedimentological, granulometric and petrographic data are presented from a detailed study on a crystal-rich mass flow deposit, which is presumably related to the eruption of a sublacustrine cryptodome. The deposit forms a prominent intercalation in the Lower Permian Collio Formation in the Italian Alps north of Brescia. Outcrops of the 10–20-m-thick volcaniclastic deposit (Dasdana I Beds, DB) can be traced over 12 km from east to west. The DB consists of a thick, crystal-rich, sandy–gravelly lower subunit representing a sequence of amalgamated Bouma-a(b) divisions overlain by a thin, well-bedded, sandy–muddy subunit that is rich in outsize porphyritic silicic fragments. Modal and computer-aided image analyses reveal that the crystal-rich lower subunit contains up to 80% of volcanogenic crystals. Some samples contain up to 60% of porphyritic fragments, which have a phenocryst content of about 20%. The wide textural range from cryptocrystalline, poikilomosaic, to rarer medium-grained granophyric groundmass, the irregular to lensoid shapes of the porphyritic fragments, and the presence of basement and sedimentary clasts suggest that the DB originated from a sublacustrine eruption of a partially extrusive cryptodome (ca. 1.6 km³). Two other porphyritic felsic cryptodomes (Dosso dei Lupi, Dosso del Bue), described briefly here, emplaced into the Collio Formation sometime after the DB event, and expose flat bases and tilted sediments at their sides. Textures observed in these domes are comparable to those found in the DB porphyritic fragments.  相似文献   

Reflections on a White Discipline     

Laura Pulido 《The Professional geographer》2002,54(1):42-49

Utilizing a partially autobiographical format, this article considers the practice and study of race within geography. I argue that the overwhelmingly white composition of the discipline has very real implications for both individual experiences and our intellectual production and disciplinary culture. I explore these issues by drawing on my own experiences as a Chicana within geography, and by examining the extent to which one area of research, environmental justice, has engaged questions of race and the consequences of that engagement. I conclude with some general remarks on what it might take to significantly diversify geography.  相似文献   

Habitat, occurrence and conservation of Saharo-Arabian-Turanian element Forsskaolea tenacissima L. in the Iberian Peninsula   总被引：1，自引：0，他引：1  

Javier Cabello  Domingo Alcaraz  Francisco Gmez-Mercado  Juan F. Mota  Javier Navarro  Julio Peas  Esther Gimnez 《Journal of Arid Environments》2003,53(4):491-500

The aim of this study is to assess the Iberian populations of Forsskaolea tenacissima L. according to its biogeographical interest, habitat, geographical range and conservation status. Results point out that they are restricted to gravel wadis of Tabernas Desert (SE Spain), are scarcely included in protected areas and represent historically isolated populations with relict behaviour. We also describe a new association, Senecioni-Forsskaoleetum tenacissimae. Conservation status of species is cause for concern and two conservation actions must be carried out. Firstly, protected areas should house Forsskaolea populations and secondly, phytosociological characterization of a community allows inventorying its habitat and directing conservation efforts to community level.  相似文献   

Atmospheric nitrogen inputs into the North Sea: effect on productivity     

Gerrit de Leeuw  Lucinda Spokes  Tim Jickells  Carsten Ambelas Skjth  Ole Hertel  Elisabetta Vignati  Susanne Tamm  Michael Schulz  Lise-Lotte Srensen  Britta Pedersen  Laura Klein  K. Heinke Schlünzen 《Continental Shelf Research》2003,23(17-19):1743

The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m⁻² day⁻¹, which has the potential to promote primary productivity of 5.3 mmol C m⁻² day⁻¹. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km⁻¹, i.e. 0.19 mmol N m⁻² day⁻¹ which has the potential to promote primary productivity of 1.2 mmol C m⁻² day⁻¹. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NO_x and NH₃ are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m⁻² day⁻¹, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m² is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem.  相似文献   

Groundwater residence times and flow paths in fractured rock determined using environmental tracers in the Mission Tunnel; Santa Barbara County,California, USA     

Laura K. Rademacher  Jordan F. Clark  James R. Boles 《Environmental Geology》2003,43(5):557-567

Multiple geochemical tracers [ion chemistry, stable isotopes of water, chlorofluorocarbons (CFC), tritium] and a 25-year-long record of discharge were used to understand residence times and flow paths of groundwater seeps in the fractured rock aquifer surrounding the Mission Tunnel, Santa Barbara, California. Tritium data from individual seeps indicate that seep waters are a mixture of >45-year-old (recharged prior to the nuclear bomb tests) and young groundwater. CFC data support this interpretation, however, a two-end member mixing model cannot completely explain the age tracer data. Microbial degradation and partial re-equilibration complicate the CFC signal. Spectral analysis of precipitation and groundwater seepage records shows that seepage lags precipitation by 3 months. This delay is related to the advancement of the wetting front and increasing the number of active flow paths. Additionally, the amount of seepage produced by precipitation is less during extended periods of drought than during normal or wet periods, suggesting antecedent conditions strongly affect flow through this fractured rock aquifer.  相似文献   

Adsorption of Copper, Nickel, and Cadmium on Goethite in the Presence of Organic Ligands   总被引：2，自引：0，他引：2  

Diane Buerge-Weirich  Philippe Behra  Laura Sigg 《Aquatic Geochemistry》2003,9(2):65-85

Adsorption of copper, cadmium and nickel at low concentrations on goethite was studied in the presence of the simple organic ligands oxalate, salicylate, and pyromellitate. The experimental metal adsorption behavior was compared to calculations with a surface complexation model to evaluate the most important interactions. Oxalate mostly decreased Cu and Ni adsorption at high pH-values by competition between solution and surface complexation but had no effect on Cd adsorption. Cu adsorption in the presence of oxalate below pH 6 could best be described by defining a ternary complex of type A (surface-metal-ligand). Salicylate had only minor effects on metal adsorption. The adsorption of Cu in the presence of salicylate above pH 5 could be explained by a ternary complex of type A. Pyromellitate increased the adsorption of Cu and Cd in the acidic pH-range, likely by formation of ternary surface complexes of type B (surface-ligand-metal).  相似文献